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1 article(s) from Uppal, Sakashi

Microelectrode arrays, electrosynthesis, and the optimization of signaling on an inert, stable surface

Kendra Drayton-White,
Siyue Liu,
Yu-Chia Chang,
Sakashi Uppal and
Kevin D. Moeller

Beilstein J. Org. Chem. 2022, 18, 1488–1498, doi:10.3762/bjoc.18.156

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Graphical Abstract

Figure 1: Natural products YM-254890 and FR-900359.

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Figure 2: Diblock copolymers used for coating microelectrode arrays.

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Figure 3: An indirect method for detecting binding events.

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Scheme 1: A Cu(I)-catalyzed cross-coupling reaction on an array.

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Figure 4: A model study using an RGD peptide (C-PEG6-GGRGDGP) and integrin receptor (α5,β1).

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Figure 5: A failure in connection with the monitoring of binding events between a peptide and its G-protein t...

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Scheme 2: An array-based Chan–Lam coupling reaction.

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Figure 6: Potential for an immediate, rapid change in current. a) The binding event being monitored has alrea...

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Figure 7: Four cycles vs. twelve cycles and the effect on binding curve location.

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Figure 8: Repeating the experiment on different arrays. (a) A comparison between a 4-cycle placement reaction...

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Figure 9: Quantitative fluorescent study on variance of the polymer coating across the microelectrode surface...

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Scheme 3: A new method for decreasing the concentration of R6A on the surface of the electrodes.

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Figure 10: An initial study and the comparison of an R6A surface and a 1:1 R6A/cysteine methyl ester surface.

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Figure 11: Calibrating the array-based signaling experiment for monitoring small molecule G-protein interactio...

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Published 20 Oct 2022

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